Communication: Mean-field theory of water-water correlations in electrolyte solutions
نویسندگان
چکیده
منابع مشابه
Modulation effects within the mean-field theory of electrolyte solutions.
The consequences of source charge and surface modulation are studied within the framework of the Poisson-Boltzmann theory of electrolyte solutions. Through a consideration of various examples, it is found that inherent modulation can lead to both like-charge attraction and overcharging effects.
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The structure of water and electrolyte solutions.
Intermolecular forces tend to organize water molecules into a tetrahedral lattice, conferring "crystalline" properties on the liquid. The simple ions, such as Na+, K+, and Cl-, have dinmensions which are of the same order as the water nmolecule. Therefore, in aqueous solution, ions can substitute for water molecules in the water lattice. However, because the force between ion and water molecule...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2017
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.4983221